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dc.contributor.authorMurillo, Edwin A.
dc.contributor.authorMejia, Maria Cristina
dc.date.accessioned2021-11-16T21:52:56Z
dc.date.available2021-11-16T21:52:56Z
dc.date.issued2016-08-04
dc.identifier.urihttp://repositorio.ufps.edu.co/handle/ufps/1026
dc.description.abstractNew functional polymers will be prepared using alkyd resins having high solid content (environmentally friendly) and comb-type structural morphology. Different copolymers of hydroxyethyl acrylate and methyl methacrylate (HEMMA) were synthesized by solution polymerization using azo-bis-(isobutyronitrile) (AIBN) as initiator and dimethylformamide as a solvent. The proportions utilized of AIBN were 0.5 (HEMMA1), 1.0 (HEMMA2), 1.5 (HEMMA3) and 2.0 wt. % (HEMMA4). The conversion percentage of the reaction was higher than 90%. The formation of the copolymers was evidenced by infrared analysis, hydroxyl value, and nuclear magnetic resonance. The intensity of OH group adsorption increased with the molecular weight and hydroxyl value. The polydispersity index was lower than 1.5. All copolymers exhibited a stable region on viscosity at a shear rate between 0.1 and 10 s–1. The copolymers exhibited good thermal stability, flexibility, and adherence.eng
dc.format.mimetypeapplication/pdfspa
dc.language.isoengspa
dc.publisherPolimerosspa
dc.relation.ispartofPolímeros
dc.rightsThis is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.eng
dc.sourcehttps://www.scielo.br/j/po/a/mhF8mjqL4MHvGHW4xQqJHFS/?format=html&lang=enspa
dc.titleStudy of the structural, thermal, rheological and film properties of functional copolymers of hydroxyethyl acrylate and methyl methacrylateeng
dc.typeArtículo de revistaspa
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dc.identifier.doihttps://doi.org/10.1590/0104-1428.1896
dc.publisher.placeBrasilia, Brasilspa
dc.relation.citationeditionVol.26 No.3.(2016)spa
dc.relation.citationendpage261spa
dc.relation.citationissue3 (2016)spa
dc.relation.citationstartpage254spa
dc.relation.citationvolume26spa
dc.relation.citesMejia, M., & Murillo, E. (2016). Study of the structural, thermal, rheological and film properties of functional copolymers of hydroxyethyl acrylate and methyl methacrylate. Polímeros, 26, 254-261.
dc.relation.ispartofjournalPolímerosspa
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.creativecommonsAtribución 4.0 Internacional (CC BY 4.0)spa
dc.subject.proposalhydroxyethyl acrylateeng
dc.subject.proposalmethyl methacrylateeng
dc.subject.proposalsynthesiseng
dc.subject.proposalcopolymerizationeng
dc.subject.proposalpropertieseng
dc.type.coarhttp://purl.org/coar/resource_type/c_6501spa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/articlespa
dc.type.redcolhttp://purl.org/redcol/resource_type/ARTspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85spa
dc.type.versioninfo:eu-repo/semantics/publishedVersionspa


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