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Waterborne hyperbranched alkyd-acrylic resin obtained by miniemulsion polymerization

dc.contributor.authorLopez, Betty
dc.contributor.authorMurillo, Edwin A.
dc.date.accessioned2021-11-16T21:28:59Z
dc.date.available2021-11-16T21:28:59Z
dc.date.issued2016-12-08
dc.identifier.urihttp://repositorio.ufps.edu.co/handle/ufps/1023
dc.description.abstractFour waterborne hyperbranched alkyd-acrylic resins (HBRAA) were synthesized by miniemulsion polymerization from a hyperbranched alkyd resin (HBR), methyl methacrylate (MMA), butyl acrylate (BA) and acrylic acid (AA), by using benzoyl peroxide (BPO) and ammonium persulfate (AP) as initiators. The reaction between HBR and acrylic monomers was evidenced by differential scanning calorimetric (DSC), nuclear magnetic resonance (NMR) and gel permeation chromatography (GPC). The conversion percentage, glass transition temperature (Tg), content of acrylic polymer (determined by soxhlet extraction) and molecular weight increased with the content of acrylic monomers used in the synthesis. The main structure formed during the synthesis was the HBRAA. The analysis by dynamic light scattering (DLS) showed that the particle size distribution of HBRAA2, HBRAA3 and HBRAA4 resins were mainly monomodal. The film properties (gloss, flexibility, adhesion and drying time) of the HBRAA were good.eng
dc.format.mimetypeapplication/pdfspa
dc.language.isoengspa
dc.publisherPolimerosspa
dc.relation.ispartofPolímeros
dc.rightsThis is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.eng
dc.sourcehttps://www.scielo.br/j/po/a/vGckBF5gxTKCBxtTKzhrVSB/?format=htmlspa
dc.titleWaterborne hyperbranched alkyd-acrylic resin obtained by miniemulsion polymerizationeng
dc.typeArtículo de revistaspa
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dc.identifier.doihttps://doi.org/10.1590/0104-1428.2344
dc.publisher.placeBrasilia , Brasilspa
dc.relation.citationeditionVol.26 No.4.(2016)spa
dc.relation.citationendpage351spa
dc.relation.citationissue4 (2016)spa
dc.relation.citationstartpage343spa
dc.relation.citationvolume26spa
dc.relation.citesMurillo, E., & López, B. (2016). Waterborne hyperbranched alkyd-acrylic resin obtained by miniemulsion polymerization. Polímeros, 26, 343-351.
dc.relation.ispartofjournalPolímerosspa
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.creativecommonsAtribución 4.0 Internacional (CC BY 4.0)spa
dc.subject.proposalhyperbranched polymerseng
dc.subject.proposalminiemulsion polymerizationeng
dc.subject.proposalalkyd-acrylic resinseng
dc.subject.proposalpropertieseng
dc.type.coarhttp://purl.org/coar/resource_type/c_6501spa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/articlespa
dc.type.redcolhttp://purl.org/redcol/resource_type/ARTspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85spa
dc.type.versioninfo:eu-repo/semantics/publishedVersionspa


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