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Hyperbranched polyester polyol plasticized tapioca starch/low density polyethylene blends
dc.contributor.author | Guzman, Manuel | |
dc.contributor.author | Giraldo, Diego | |
dc.contributor.author | Murillo, Edwin A. | |
dc.date.accessioned | 2021-11-16T19:43:25Z | |
dc.date.available | 2021-11-16T19:43:25Z | |
dc.date.issued | 2017 | |
dc.identifier.uri | http://repositorio.ufps.edu.co/handle/ufps/1016 | |
dc.description.abstract | In this work, low density polyethylene (LDPE)/plasticized starch (TPS) blends were prepared. The TPS employed in this study was obtained by plasticization of tapioca starch with a hyperbranched polyester polyol. Differential scanning calorimetry analysis showed that the melting temperature increased with the TPS content. The opposite effect was exhibited in the crystallization temperature and additional changes were not observed during the heating. X-ray diffraction analysis showed a reduction in intensity of the peak at Bragg’s angle 17.5°, proving a diminution on A type crystallinity with the increasing amount of LDPE. Micrographs obtained by scanning electron microscopy exhibited starch granules without destructure. TPS acted as a filler to LDPE, since the mechanical properties (Young’s modulus and tensile strength) improved ostensibly. The Young’ modulus and tensile strength decreased with the amount of LDPE, however, the elongation at break exhibited an opposite behavior. | eng |
dc.format.mimetype | application/pdf | spa |
dc.language.iso | eng | spa |
dc.publisher | Polimeros | spa |
dc.relation.ispartof | Polímeros | |
dc.rights | This is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. | eng |
dc.source | https://www.scielo.br/j/po/a/DGYnRJNwsLDDTHf8p7rBVvB/?lang=en&format=html | spa |
dc.title | Hyperbranched polyester polyol plasticized tapioca starch/low density polyethylene blends | eng |
dc.type | Artículo de revista | spa |
dcterms.references | Rodriguez-Gonzalez, F. J., Ramsay, B. A., & Favis, B. D. (2003). High performance LDPE/thermoplastic starch blends: a sustainable alternative to pure polyethylene. Polymer, 44(5), 1517-1526. http://dx.doi.org/10.1016/S0032-3861(02)00907-2 | spa |
dcterms.references | Da Róz, A., Carvalho, A., Gandini, I. A., & Curvelo, A. (2006). The effect of plasticizers on thermoplastic starch compositions obtained by melt processing. Carbohydrate Polymers, 63(3), 417-424. http://dx.doi.org/10.1016/j.carbpol.2005.09.017 | spa |
dcterms.references | Chillo, S., Flores, S., Mastromatteo, M., Conte, A., Gerschenson, L., & Del Nobile, M. A. (2008). Influence of glycerol and chitosan on tapioca starch-based edible film properties. Journal of Food Engineering, 88(2), 159-168. http://dx.doi.org/10.1016/j.jfoodeng.2008.02.002 | spa |
dcterms.references | Ma, X. F., Yu, J. G., & Wan, J. J. (2006). Urea and ethanolamine as a mixed plasticizer for thermoplastic starch. Carbohydrate Polymers, 64(2), 267-273. http://dx.doi.org/10.1016/j.carbpol.2005.11.042 | spa |
dcterms.references | Yang, J., Yu, J., & Ma, X. (2006). Study on the properties of ethylenebisformamide and sorbitol plasticized corn starch (ESPTPS). Carbohydrate Polymers, 66(1), 110-116. http://dx.doi.org/10.1016/j.carbpol.2006.02.029 | spa |
dcterms.references | Murillo, E. A., Cardona, A., & López, B. L. (2011). Rheological behavior in the molten state and solution of hyperbranched polyester of fourth and fifth generation. Journal of Applied Polymer Science, 119(2), 929-935. http://dx.doi.org/10.1002/app.32774 | spa |
dcterms.references | Murillo, E. A., Vallejo, P. P., & López, B. L. (2010). Characterization of hydroxylated hyperbranched polyesters of fourth and fifth generation. E-Polymers, 120(1), 1-12. http://dx.doi.org/10.1515/epoly.2010.10.1.1347 | spa |
dcterms.references | Murillo, E. A., Vallejo, P. P., Sierra, L., & López, B. L. (2009). Characterization of hyperbranched polyol polyesters based on 2,2-bis (methylol propionic acid) and pentaerythritol. Journal of Applied Polymer Science, 112(1), 200-207. http://dx.doi.org/10.1002/app.29397 | spa |
dcterms.references | Murillo, E. A., Vallejo, P. P., & López, B. L. (2010). Synthesis and characterization of hyperbranched alkyd resins based on tall oil fatty acids. Progress in Organic Coatings, 69(3), 235-240. http://dx.doi.org/10.1016/j.porgcoat.2010.04.018 | spa |
dcterms.references | Sailaja, R. R. N., & Seetharamu, S. (2008). Itaconic acid - grafted - LDPE as compatibilizer for LDPE - plasticized Tapioca starch blends. Reactive & Functional Polymers, 68(4), 831-841. http://dx.doi.org/10.1016/j.reactfunctpolym.2007.12.003 | spa |
dcterms.references | Guzmán, M., & Murillo, E. A. (2014). Funcionalización de polietileno de baja densidad con anhídrido maleico en estado fundido. Polímeros: Ciência e Tecnologia, 24(2), 162-169. http://dx.doi.org/10.4322/polimeros.2014.034 | spa |
dcterms.references | St-Pierre, N., Favis, B. D., Ramsay, B. A., Ramsay, J. A., & Verhoogt, H. (1997). Processing and characterization of thermoplastic starch/polyethylene blends. Polymer, 38(3), 647-655. http://dx.doi.org/10.1016/S0032-3861(97)81176-7 | spa |
dcterms.references | Halley, P. J., Truss, R. W., Markotsis, M. G., Chaleat, C., Russo, M., Sargent, A. L., Tan, I., & Sopade, P. A. (2007). Review of biodegradable thermoplastic starch polymers. ACS Symposium Series, 978, 287-300. http://dx.doi.org/10.1021/bk-2007-0978.ch024 | spa |
dcterms.references | Pedroso, A., & Rosa, D. (2005). Mechanical, thermal and morphological characterization of recycled LDPE/corn starch blends. Carbohydrate Polymers, 59(1), 1-9. http://dx.doi.org/10.1016/j.carbpol.2004.08.018 | spa |
dcterms.references | Ning, W., Jiugao, Y., Xiaofei, M., & Ying, W. (2007). The influence of citric acid on the properties of thermoplastic starch/linear low-density polyethylene blends. Carbohydrate Polymers, 67(3), 446-453. http://dx.doi.org/10.1016/j.carbpol.2006.06.014 | spa |
dcterms.references | Garg, S., & Jana, A. K. (2007). Studies on the properties and characteristics of starch-LDPE blend films using cross-linked, glycerol modified, cross-linked and glycerol modified starch. European Polymer Journal, 43(9), 3976-3987. http://dx.doi.org/10.1016/j.eurpolymj.2007.06.030 | spa |
dcterms.references | Guzmán, M., & Murillo, E. A. (2015). The properties of blends of maleic - anhydride - grafted polyethylene and thermoplastic starch using hyperbranched polyester polyol as a plasticizer. Polymer Engineering and Science, 55(11), 2526-2533. http://dx.doi.org/10.1002/pen.24143 | spa |
dcterms.references | Zaky, M. T., & Mohamed, N. H. (2010). Influence of low-density polyethylene on the thermal characteristics and crystallinity of high melting point macro- and micro-crystalline waxes. Thermochimica Acta, 499(1-2), 79-84. http://dx.doi.org/10.1016/j.tca.2009.11.005 | spa |
dcterms.references | Pushpadass, H. A., Bhandari, P., & Hanna, M. A. (2010). Effects of LDPE and glycerol contents and compounding on the microstructure and properties of starch composite films. Carbohydrate Polymers, 82(4), 1082-1089. http://dx.doi.org/10.1016/j.carbpol.2010.06.032 | spa |
dcterms.references | Mandani, M. (2010). Structure, optical and thermal decomposition characters of LDPE graft copolymers synthesized by gamma irradiation. Materials Science, 33, 65-73. http://dx.doi.org/10.1016/j.cap.2010.06.021 | spa |
dcterms.references | Ning, W., Jiugao, Y., Xiaofei, M., & Chunmei, H. (2007). High performance modified thermoplastic starch/linear low-density polyethylene blends in one-step extrusion. Polymer Composites, 28(1), 89-97. http://dx.doi.org/10.1002/pc.20266 | spa |
dcterms.references | Leclair, A., & Favis, B. D. (1996). The role of interfacial contact in immiscible binary polymer blends and its influence on mechanical properties. Polymer, 37(21), 4723-4728. http://dx.doi.org/10.1016/S0032-3861(96)00319-9 | spa |
dc.identifier.doi | https://doi.org/10.1590/0104-1428.04816 | |
dc.publisher.place | Brasilia , Brasil | spa |
dc.relation.citationedition | Vol.27 No.1.(2017) | spa |
dc.relation.citationendpage | 7 | spa |
dc.relation.citationissue | 1 (2017) | spa |
dc.relation.citationstartpage | 1 | spa |
dc.relation.citationvolume | 27 | spa |
dc.relation.cites | Guzmán, M., Giraldo, D., & Murillo, E. (2017). Hyperbranched polyester polyol plasticized tapioca starch/low density polyethylene blends. Polímeros, 27, 1-7. | |
dc.relation.ispartofjournal | Polímeros | spa |
dc.rights.accessrights | info:eu-repo/semantics/openAccess | spa |
dc.rights.creativecommons | Atribución 4.0 Internacional (CC BY 4.0) | spa |
dc.subject.proposal | LDPE | eng |
dc.subject.proposal | thermoplastic starch | eng |
dc.subject.proposal | blends | eng |
dc.subject.proposal | properties | eng |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | spa |
dc.type.content | Text | spa |
dc.type.driver | info:eu-repo/semantics/article | spa |
dc.type.redcol | http://purl.org/redcol/resource_type/ART | spa |
oaire.accessrights | http://purl.org/coar/access_right/c_abf2 | spa |
oaire.version | http://purl.org/coar/version/c_970fb48d4fbd8a85 | spa |
dc.type.version | info:eu-repo/semantics/publishedVersion | spa |