Mostrar el registro sencillo del ítem

dc.contributor.authorGuzman, Manuel
dc.contributor.authorGiraldo, Diego
dc.contributor.authorMurillo, Edwin A.
dc.date.accessioned2021-11-16T19:43:25Z
dc.date.available2021-11-16T19:43:25Z
dc.date.issued2017
dc.identifier.urihttp://repositorio.ufps.edu.co/handle/ufps/1016
dc.description.abstractIn this work, low density polyethylene (LDPE)/plasticized starch (TPS) blends were prepared. The TPS employed in this study was obtained by plasticization of tapioca starch with a hyperbranched polyester polyol. Differential scanning calorimetry analysis showed that the melting temperature increased with the TPS content. The opposite effect was exhibited in the crystallization temperature and additional changes were not observed during the heating. X-ray diffraction analysis showed a reduction in intensity of the peak at Bragg’s angle 17.5°, proving a diminution on A type crystallinity with the increasing amount of LDPE. Micrographs obtained by scanning electron microscopy exhibited starch granules without destructure. TPS acted as a filler to LDPE, since the mechanical properties (Young’s modulus and tensile strength) improved ostensibly. The Young’ modulus and tensile strength decreased with the amount of LDPE, however, the elongation at break exhibited an opposite behavior.eng
dc.format.mimetypeapplication/pdfspa
dc.language.isoengspa
dc.publisherPolimerosspa
dc.relation.ispartofPolímeros
dc.rightsThis is an Open Access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.eng
dc.sourcehttps://www.scielo.br/j/po/a/DGYnRJNwsLDDTHf8p7rBVvB/?lang=en&format=htmlspa
dc.titleHyperbranched polyester polyol plasticized tapioca starch/low density polyethylene blendseng
dc.typeArtículo de revistaspa
dcterms.referencesRodriguez-Gonzalez, F. J., Ramsay, B. A., & Favis, B. D. (2003). High performance LDPE/thermoplastic starch blends: a sustainable alternative to pure polyethylene. Polymer, 44(5), 1517-1526. http://dx.doi.org/10.1016/S0032-3861(02)00907-2spa
dcterms.referencesDa Róz, A., Carvalho, A., Gandini, I. A., & Curvelo, A. (2006). The effect of plasticizers on thermoplastic starch compositions obtained by melt processing. Carbohydrate Polymers, 63(3), 417-424. http://dx.doi.org/10.1016/j.carbpol.2005.09.017spa
dcterms.referencesChillo, S., Flores, S., Mastromatteo, M., Conte, A., Gerschenson, L., & Del Nobile, M. A. (2008). Influence of glycerol and chitosan on tapioca starch-based edible film properties. Journal of Food Engineering, 88(2), 159-168. http://dx.doi.org/10.1016/j.jfoodeng.2008.02.002spa
dcterms.referencesMa, X. F., Yu, J. G., & Wan, J. J. (2006). Urea and ethanolamine as a mixed plasticizer for thermoplastic starch. Carbohydrate Polymers, 64(2), 267-273. http://dx.doi.org/10.1016/j.carbpol.2005.11.042spa
dcterms.referencesYang, J., Yu, J., & Ma, X. (2006). Study on the properties of ethylenebisformamide and sorbitol plasticized corn starch (ESPTPS). Carbohydrate Polymers, 66(1), 110-116. http://dx.doi.org/10.1016/j.carbpol.2006.02.029spa
dcterms.referencesMurillo, E. A., Cardona, A., & López, B. L. (2011). Rheological behavior in the molten state and solution of hyperbranched polyester of fourth and fifth generation. Journal of Applied Polymer Science, 119(2), 929-935. http://dx.doi.org/10.1002/app.32774spa
dcterms.referencesMurillo, E. A., Vallejo, P. P., & López, B. L. (2010). Characterization of hydroxylated hyperbranched polyesters of fourth and fifth generation. E-Polymers, 120(1), 1-12. http://dx.doi.org/10.1515/epoly.2010.10.1.1347spa
dcterms.referencesMurillo, E. A., Vallejo, P. P., Sierra, L., & López, B. L. (2009). Characterization of hyperbranched polyol polyesters based on 2,2-bis (methylol propionic acid) and pentaerythritol. Journal of Applied Polymer Science, 112(1), 200-207. http://dx.doi.org/10.1002/app.29397spa
dcterms.referencesMurillo, E. A., Vallejo, P. P., & López, B. L. (2010). Synthesis and characterization of hyperbranched alkyd resins based on tall oil fatty acids. Progress in Organic Coatings, 69(3), 235-240. http://dx.doi.org/10.1016/j.porgcoat.2010.04.018spa
dcterms.referencesSailaja, R. R. N., & Seetharamu, S. (2008). Itaconic acid - grafted - LDPE as compatibilizer for LDPE - plasticized Tapioca starch blends. Reactive & Functional Polymers, 68(4), 831-841. http://dx.doi.org/10.1016/j.reactfunctpolym.2007.12.003spa
dcterms.referencesGuzmán, M., & Murillo, E. A. (2014). Funcionalización de polietileno de baja densidad con anhídrido maleico en estado fundido. Polímeros: Ciência e Tecnologia, 24(2), 162-169. http://dx.doi.org/10.4322/polimeros.2014.034spa
dcterms.referencesSt-Pierre, N., Favis, B. D., Ramsay, B. A., Ramsay, J. A., & Verhoogt, H. (1997). Processing and characterization of thermoplastic starch/polyethylene blends. Polymer, 38(3), 647-655. http://dx.doi.org/10.1016/S0032-3861(97)81176-7spa
dcterms.referencesHalley, P. J., Truss, R. W., Markotsis, M. G., Chaleat, C., Russo, M., Sargent, A. L., Tan, I., & Sopade, P. A. (2007). Review of biodegradable thermoplastic starch polymers. ACS Symposium Series, 978, 287-300. http://dx.doi.org/10.1021/bk-2007-0978.ch024spa
dcterms.referencesPedroso, A., & Rosa, D. (2005). Mechanical, thermal and morphological characterization of recycled LDPE/corn starch blends. Carbohydrate Polymers, 59(1), 1-9. http://dx.doi.org/10.1016/j.carbpol.2004.08.018spa
dcterms.referencesNing, W., Jiugao, Y., Xiaofei, M., & Ying, W. (2007). The influence of citric acid on the properties of thermoplastic starch/linear low-density polyethylene blends. Carbohydrate Polymers, 67(3), 446-453. http://dx.doi.org/10.1016/j.carbpol.2006.06.014spa
dcterms.referencesGarg, S., & Jana, A. K. (2007). Studies on the properties and characteristics of starch-LDPE blend films using cross-linked, glycerol modified, cross-linked and glycerol modified starch. European Polymer Journal, 43(9), 3976-3987. http://dx.doi.org/10.1016/j.eurpolymj.2007.06.030spa
dcterms.referencesGuzmán, M., & Murillo, E. A. (2015). The properties of blends of maleic - anhydride - grafted polyethylene and thermoplastic starch using hyperbranched polyester polyol as a plasticizer. Polymer Engineering and Science, 55(11), 2526-2533. http://dx.doi.org/10.1002/pen.24143spa
dcterms.referencesZaky, M. T., & Mohamed, N. H. (2010). Influence of low-density polyethylene on the thermal characteristics and crystallinity of high melting point macro- and micro-crystalline waxes. Thermochimica Acta, 499(1-2), 79-84. http://dx.doi.org/10.1016/j.tca.2009.11.005spa
dcterms.referencesPushpadass, H. A., Bhandari, P., & Hanna, M. A. (2010). Effects of LDPE and glycerol contents and compounding on the microstructure and properties of starch composite films. Carbohydrate Polymers, 82(4), 1082-1089. http://dx.doi.org/10.1016/j.carbpol.2010.06.032spa
dcterms.referencesMandani, M. (2010). Structure, optical and thermal decomposition characters of LDPE graft copolymers synthesized by gamma irradiation. Materials Science, 33, 65-73. http://dx.doi.org/10.1016/j.cap.2010.06.021spa
dcterms.referencesNing, W., Jiugao, Y., Xiaofei, M., & Chunmei, H. (2007). High performance modified thermoplastic starch/linear low-density polyethylene blends in one-step extrusion. Polymer Composites, 28(1), 89-97. http://dx.doi.org/10.1002/pc.20266spa
dcterms.referencesLeclair, A., & Favis, B. D. (1996). The role of interfacial contact in immiscible binary polymer blends and its influence on mechanical properties. Polymer, 37(21), 4723-4728. http://dx.doi.org/10.1016/S0032-3861(96)00319-9spa
dc.identifier.doihttps://doi.org/10.1590/0104-1428.04816
dc.publisher.placeBrasilia , Brasilspa
dc.relation.citationeditionVol.27 No.1.(2017)spa
dc.relation.citationendpage7spa
dc.relation.citationissue1 (2017)spa
dc.relation.citationstartpage1spa
dc.relation.citationvolume27spa
dc.relation.citesGuzmán, M., Giraldo, D., & Murillo, E. (2017). Hyperbranched polyester polyol plasticized tapioca starch/low density polyethylene blends. Polímeros, 27, 1-7.
dc.relation.ispartofjournalPolímerosspa
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.rights.creativecommonsAtribución 4.0 Internacional (CC BY 4.0)spa
dc.subject.proposalLDPEeng
dc.subject.proposalthermoplastic starcheng
dc.subject.proposalblendseng
dc.subject.proposalpropertieseng
dc.type.coarhttp://purl.org/coar/resource_type/c_6501spa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/articlespa
dc.type.redcolhttp://purl.org/redcol/resource_type/ARTspa
oaire.accessrightshttp://purl.org/coar/access_right/c_abf2spa
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85spa
dc.type.versioninfo:eu-repo/semantics/publishedVersionspa


Ficheros en el ítem

Thumbnail

Este ítem aparece en la(s) siguiente(s) colección(ones)

Mostrar el registro sencillo del ítem