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dc.contributor.authorBecerra Moreno, Dorance
dc.contributor.authorSOTO VERJEL, JOSEPH WBEIMAR
dc.contributor.authorVillamizar, Salvador
dc.contributor.authorMachuca-Martinez, Fiderman
dc.contributor.authorRamírez Ríos, Luisa Fernanda
dc.date.accessioned2021-11-27T23:44:45Z
dc.date.available2021-11-27T23:44:45Z
dc.date.issued2020-05-28
dc.identifier.urihttp://repositorio.ufps.edu.co/handle/ufps/1508
dc.description.abstractIn the present study, the use of heterogeneous photocatalysis TiO2/UV coupled to an activated sludge reactor was evaluated as an alternative treatment for the leachate coming from a Landfll, located in Cucuta (Colombia). TiO2 (Degussa P-25) between 100 and 600 mg.L−1 was used as a catalyst, semi-continuous type reactors for the photocatalysis, a batch for the biological stage, UV light with accumulated energies from 20 to 60 kJ.L−1 were also used, a constant concentration of H2O2 was used as an adjuvant in all tests. The research consisted of four main phases: leachate characterization, biological treatment, optimization of photocatalytic and AOP-biological coupling. For the optimization of the photocatalytic step, an experimental design was carried out through the statistical program Statgraphics Centurion XV of factorial type 3^2 (3 levels 2 variables), modeling the results by means of a response surface, the variables of the pH and the concentration of the catalyst were included, having this as input for the response of interest the percentage (%) of DOC removal. The biological process itself provided a removal of 38 and 24% for COD and DOC, respectively. The AOP-biological coupling provided a removal of 68 and 76% in terms of COD and DOC, respectively. Thus, the coupling signifcantly improves the overall efciency of the process by more than 50%, which represents a promising improvement compared to the removal of organic matter for the treatment of the same type of water using only the biological process. The results show a viable alternative for the treatment of leachate because higher removal levels are achieved in residence times, which are considered shorter than the ones in conventional processes.eng
dc.format.extent14 páginasspa
dc.format.mimetypeapplication/pdfspa
dc.language.isoengspa
dc.publisherTopics in Catalysisspa
dc.relation.ispartofTopics in Catalysis ISSN: 1572-9028, 2020 vol:63 fasc: N/A págs: 1 - 14, DOI:10.1007/s11244-020-01284-1
dc.rightsSpringer Science+Business Media, LLC, part of Springer Nature 2020eng
dc.sourcehttps://link.springer.com/article/10.1007%2Fs11244-020-01284-1spa
dc.titleAlternative for the Treatment of Leachates Generated in a Landfll of Norte de Santander–Colombia, by Means of the Coupling of a Photocatalytic and Biological Aerobic Processeng
dc.typeArtículo de revistaspa
dcterms.referencesPastore C et al (2018) Comparison of different types of landfill leachate treatments by employment of nontarget screening to identify residual refractory organics and principal component analysis. Sci Total Environ 635:984–994. https://doi.org/10.1016/j.scitotenv.2018.04.135spa
dcterms.referencesVahabian M, Hassanzadeh Y, Marofi S (2019) Assessment of landfill leachate in semi-arid climate and its impact on the groundwater quality case study: Hamedan, Iran. Environ Monit Assess 191(2):1–19. https://doi.org/10.1007/s10661-019-7215-8spa
dcterms.referencesRueda-Marquez JJ, Levchuk I, Fernández Ibañez P, Sillanpää M (2020) A critical review on application of photocatalysis for toxicity reduction of real wastewaters. J. Clean. Prod. 258:120694. https://doi.org/10.1016/j.jclepro.2020.120694spa
dcterms.referencesChemlal R et al (2014) Combination of advanced oxidation and biological processes for the landfill leachate treatment. Ecol Eng 73:281–289. https://doi.org/10.1016/j.ecoleng.2014.09.043spa
dcterms.referencesHe H, Ma H, Liu L (2020) Combined photocatalytic pre-oxidation reactor and sequencing batch bioreactor for advanced treatment of industrial wastewater. J Water Process Eng 36:101259. https://doi.org/10.1016/j.jwpe.2020.101259spa
dcterms.referencesElleuch L et al (2020) A new insight into highly contaminated landfill leachate treatment using Kefir grains pre-treatment combined with Ag-doped TiO2 photocatalytic process. J Hazard Mater 382:121119. https://doi.org/10.1016/j.jhazmat.2019.121119spa
dcterms.referencesHassan M, Wang X, Wang F, Wu D, Hussain A, Xie B (2017) Coupling ARB-based biological and photochemical (UV/TiO 2 and UV/S 2 O 8 2− ) techniques to deal with sanitary landfill leachate. Waste Manag 63:292–298. https://doi.org/10.1016/j.wasman.2016.09.003spa
dcterms.referencesPadovan RN, Azevedo EB (2015) Combining A Sequencing Batch Reactor With Heterogeneous Photocatalysis (TiO2/UV) For Treating A Pencil Manufacturer’s Wastewater. Brazilian J Chem Eng 32(1):99–106. https://doi.org/10.1590/0104-6632.20150321s00003103spa
dcterms.referencesSilva LS, Gonçalves MMM, Raddi de Araujo LR (2019) Combined photocatalytic and biological process for textile wastewater treatments. Water Environ Res 91(11):1490–1497. https://doi.org/10.1002/wer.1143spa
dcterms.referencesBorges ME, Sierra M, Méndez-Ramos J, Acosta-Mora P, Ruiz-Morales JC, Esparza P (2016) Solar degradation of contaminants in water: TiO2 solar photocatalysis assisted by up-conversion luminescent materials. Sol Energy Mater Sol Cells 155:194–201. https://doi.org/10.1016/j.solmat.2016.06.010spa
dcterms.referencesTalwar S, Sangal VK, Verma A (2018) Feasibility of using combined TiO2 photocatalysis and RBC process for the treatment of real pharmaceutical wastewater. J Photochem Photobiol A Chem 353:263–270. https://doi.org/10.1016/j.jphotochem.2017.11.013spa
dcterms.referencesVela N et al (2018) Photocatalytic oxidation of six pesticides listed as endocrine disruptor chemicals from wastewater using two different TiO2 samples at pilot plant scale under sunlight irradiation. J Photochem Photobiol A Chem 353:271–278. https://doi.org/10.1016/j.jphotochem.2017.11.040spa
dcterms.referencesD. Becerra Moreno, “Acople De Procesos Fotocatalíticos Y Biológicos Para El Tratamiento De Aguas Residuales Con Residuos De Plaguicidas,” Universidad Del Valle, 2010.spa
dcterms.referencesOCDE (Organización para la cooperación y el desarrollo económico), “Lodos Activados, Prueba de Inhibición de la Respiración (Oxidación de Carbono y Amonio),” 1998.spa
dcterms.referencesOCDE (Organización para la cooperación y el desarrollo económico), “Ensayo de Biodegradabilidad Inherente: OECD302 Zahn-Wellens / Método EMPA,” 1992.spa
dcterms.referencesHassan M, Zhao Y, Xie B (2016) Employing TiO 2 photocatalysis to deal with landfill leachate: Current status and development. Chem Eng J 285:264–275. https://doi.org/10.1016/j.cej.2015.09.093spa
dcterms.referencesMalini TP, Selvi JA, Arthanareeswari M, Kamaraj P (2019) Photocatalytic Degradation of Organo Phosphorus Herbicide Anilofos in Aqueous Solution Using TiO2 (Degussa P25) Photocatalyst. Mater Today Proc 14:574–579. https://doi.org/10.1016/j.matpr.2019.04.181spa
dcterms.referencesAmmari Y, El Atmani K, Bay L, Bakas I, Qourzal S, Ait Ichou I (2020) Elimination of a mixture of two dyes by photocatalytic degradation based on TiO2 P-25 Degussa. Mater. Today Proc 22:126–129. https://doi.org/10.1016/j.matpr.2019.08.142spa
dcterms.referencesCai F-F, Yang Z-H, Huang J, Zeng G-M, Wang L, Yang J (2014) Application of cetyltrimethylammonium bromide bentonite–titanium dioxide photocatalysis technology for pretreatment of aging leachate. J Hazard Mater 275:63–71. https://doi.org/10.1016/j.jhazmat.2014.04.050spa
dcterms.referencesMurgolo S et al (2017) A new supported TiO 2 film deposited on stainless steel for the photocatalytic degradation of contaminants of emerging concern. Chem Eng J 318:103–111. https://doi.org/10.1016/j.cej.2016.05.125spa
dcterms.referencesAbdel-Maksoud YK, Imam E, Ramadan AR (2018) Sand supported TiO2 photocatalyst in a tray photo-reactor for the removal of emerging contaminants in wastewater. Catal Today 313:55–62. https://doi.org/10.1016/j.cattod.2017.10.029spa
dcterms.referencesSaggioro EM et al (2014) Solar CPC pilot plant photocatalytic degradation of bisphenol A in waters and wastewaters using suspended and supported-TiO2. Influence of photogenerated species. Environ Sci Pollut Res 21(21):12112–12121. https://doi.org/10.1007/s11356-014-2723-0spa
dcterms.referencesHossain MK et al (2018) A comparative study on the influence of pure anatase and Degussa-P25 TiO2 nanomaterials on the structural and optical properties of dye sensitized solar cell (DSSC) photoanode. Optik (Stuttg) 171:507–516. https://doi.org/10.1016/j.ijleo.2018.05.032spa
dcterms.referencesPrieto-Rodriguez L, Miralles-Cuevas S, Oller I, Agüera A, Puma GL, Malato S (2012) Treatment of emerging contaminants in wastewater treatment plants (WWTP) effluents by solar photocatalysis using low TiO2 concentrations. J Hazard Mater 211–212:131–137. https://doi.org/10.1016/j.jhazmat.2011.09.008spa
dcterms.referencesMiranda SM et al (2015) Solar photocatalytic gas-phase degradation of n-decane—a comparative study using cellulose acetate monoliths coated with P25 or sol-gel TiO2 films. Environ Sci Pollut Res 22(2):820–832. https://doi.org/10.1007/s11356-014-2952-2spa
dcterms.referencesOhtani B, Prieto-Mahaney OO, Li D, Abe R (2010) What is Degussa (Evonik) P25? Crystalline composition analysis, reconstruction from isolated pure particles and photocatalytic activity test. J Photochem Photobiol A Chem 216(2–3):179–182. https://doi.org/10.1016/j.jphotochem.2010.07.024spa
dcterms.referencesJoseph K, Raj A, Viswanathan B (2009) Effect of surface area, pore volume and particle size of P25 titania on the phase transformation of anatase to rutile. Indian J Chem 48:1378–1382spa
dcterms.referencesLachheb H, Guillard C, Lassoued H, Haddaji M, Rajah M, Houas A (2017) Photochemical oxidation of styrene in acetonitrile solution in presence of H 2 O 2, TiO 2 /H 2 O 2 and ZnO/H 2 O 2. J Photochem Photobiol A Chem 346:462–469. https://doi.org/10.1016/j.jphotochem.2017.06.026spa
dcterms.referencesHan E, Vijayarangamuthu K, Youn J, Park Y-K, Jung S-C, Jeon K-J (2018) Degussa P25 TiO 2 modified with H 2 O 2 under microwave treatment to enhance photocatalytic properties. Catal Today 303:305–312. https://doi.org/10.1016/j.cattod.2017.08.057spa
dcterms.referencesFu D, Huang Y, Zhang X, Kurniawan TA, Ouyang T (2017) Uncovering potentials of integrated TiO2(B) nanosheets and H2O2 for removal of tetracycline from aqueous solution. J Mol Liq 248:112–120. https://doi.org/10.1016/j.molliq.2017.10.020spa
dcterms.referencesSpasiano D, Marotta R, Malato S, Fernandez-Ibañez P, Di Somma I (2015) Solar photocatalysis: Materials, reactors, some commercial, and pre-industrialized applications. A comprehensive approach. Appl Catal B 170–171:90–123. https://doi.org/10.1016/j.apcatb.2014.12.050spa
dcterms.referencesBorges ME, Sierra M, Cuevas E, García RD, Esparza P (2016) Photocatalysis with solar energy: Sunlight-responsive photocatalyst based on TiO2 loaded on a natural material for wastewater treatment. Sol Energy 135:527–535. https://doi.org/10.1016/j.solener.2016.06.022spa
dcterms.referencesD. R. Giraldo Valentín, “Eficiencia del proceso de fotocatálisis heterogénea con tio2 y h2o2 en la reducción de dbo5 y dqo de los lixiviados del botadero la mejorada el tambo Huancayo,” Repos. Inst. - UAP, 2016.spa
dcterms.referencesRocha EMR, Vilar JP, Fonseca A, Saraiva I, Boaventura RAR (2011) Landfill leachate treatment by solar-driven AOPs/H 2 O 2; Fe 2+ /H 2 O 2 /UV; TiO 2 /H 2 O 2 /UV; Pilot Plant with CPCs. Sol Energy 85:46–56. https://doi.org/10.1016/j.solener.2010.11.001spa
dcterms.referencesLM Losada, EJL Castillo, EAO Restrepo, EAS Galvis, RAT Palma, (2017) “Tratamiento de aguas contaminadas con colorantes mediante fotocatálisis con TiO2 usando luz artificial y solar. Prod + Limpia, 12(2)spa
dcterms.referencesR. Ramalho, “Introduction to Wastewater Treatment Processes - R Ramalho - Google Libros,” 1977, 403.spa
dcterms.referencesBecerra D et al (2020) Coupling of heterogeneous photocatalysis and aerobic biological process of activated sludge to treat wastewater containing Chlorpyrifos. Ing Y Compet Rev CIENTÍFICA y TECNOLÓGICA 22:13. https://doi.org/10.25100/iyc.v22i1.8135spa
dcterms.referencesE. A. Solana, “Contribución al tratamiento de lixiviados de vertedero de residuos sólidos urbanos mediante procesos de oxidación avanzada,” Universidad de Cantabria, departamento de Ingeniería Química y Orgánica, España, 2013.spa
dcterms.referencesWiszniowski J, Robert D, Surmacz-Gorska J, Miksch K, Weber J (2006) Leachate detoxification by combination of biological and TiO2-photocatalytic processes. Water Sci Technol 53:181–190spa
dcterms.referencesS. P. Cho, S. C. Hong, and S.-I. Hong, “Photocatalytic degradation of the landfill leachate containing refractory matters and nitrogen compounds,” 2002.spa
dcterms.referencesArshad R et al (2020) Degradation product distribution of Reactive Red-147 dye treated by UV/H2O2/TiO2 advanced oxidation process. J Mater Res Technol. https://doi.org/10.1016/j.jmrt.2020.01.062spa
dcterms.referencesBoutiti A, Zouaghi R, Bendjabeur SE, Guittonneau S, Sehili T (2017) Photodegradation of 1-hexyl-3-methylimidazolium by UV/H2O2 and UV/TiO2: Influence of pH and chloride. J Photochem Photobiol A Chem 336:164–169. https://doi.org/10.1016/j.jphotochem.2016.12.030spa
dcterms.referencesKaabeche ONEH, Zouaghi R, Boukhedoua S, Bendjabeur S, Sehili T (2019) A Comparative Study on Photocatalytic Degradation of Pyridinium Based Ionic Liquid by TiO2 and ZnO in Aqueous Solution. Int J Chem React Eng. https://doi.org/10.1515/ijcre-2018-0253spa
dcterms.referencesA. Mahmoodi, S. Mahmood Mehdinia, A. Rahmani, and H. Nassehinia, “IRANIAN JOURNAL OF CATALYSIS Investigation efficiency of nano photocatalytic compound of TiO 2 and rice husk silica in removal of reactive red 198 dye from synthetic aqueous solutions.”spa
dcterms.referencesLu D, Yang M, Fang P, Li C, Jiang L (2017) Enhanced photocatalytic degradation of aqueous phenol and Cr(VI) over visible-light-driven Tb x O y loaded TiO 2 -oriented nanosheets. Appl Surf Sci 399:167–184. https://doi.org/10.1016/j.apsusc.2016.12.077spa
dcterms.referencesChen D et al (2020) Photocatalytic degradation of organic pollutants using TiO2-based photocatalysts: A review. J. Clean. Prod. https://doi.org/10.1016/j.jclepro.2020.121725spa
dcterms.referencesMoreira NFF et al (2018) Solar treatment (H2O2, TiO2-P25 and GO-TiO2 photocatalysis, photo-Fenton) of organic micropollutants, human pathogen indicators, antibiotic resistant bacteria and related genes in urban wastewater. Water Res 135:195–206. https://doi.org/10.1016/j.watres.2018.01.064spa
dcterms.referencesLuo H, Zeng Y, Cheng Y, He D, Pan X (2020) Recent advances in municipal landfill leachate: A review focusing on its characteristics, treatment, and toxicity assessment. Sci Total Environ. https://doi.org/10.1016/j.scitotenv.2019.135468spa
dcterms.referencesMoraes Da Costa F, Dario S, Daflon A, Bila DM, Valeria Da Fonseca F, Campos JC (2018) Evaluation of the biodegradability and toxicity of landfill leachates after pretreatment using advanced oxidative processes. Waste Manag 76:606–613. https://doi.org/10.1016/j.wasman.2018.02.030spa
dcterms.referencesSilva TFCV et al (2013) Multistage treatment system for raw leachate fromsanitary landfill combining biological nitrification-denitrification/solar photo-Fenton/biological processes, at a scale close to industrial - Biodegradability enhancement and evolution profile of trace pol. Water Res 47(16):6167–6186. https://doi.org/10.1016/j.watres.2013.07.036spa
dcterms.referencesWang K, Li L, Tan F, Wu D (2018) Treatment of Landfill Leachate Using Activated Sludge Technology: A Review. Archaea. https://doi.org/10.1155/2018/1039453spa
dcterms.referencesCastillo E, Vergara M, Moreno Y (2006) “Landfill leachate treatment using a rotating biological contactor and an upward-flow anaerobic sludge bed reactor. Waste Manage. https://doi.org/10.1016/j.wasman.2006.08.003spa
dcterms.referencesArij Y et al (2018) “Performance of pilot scale anaerobic biofilm digester (ABD) for the treatment of leachate from a municipal waste transfer station. Biores Technol. https://doi.org/10.1016/j.biortech.2018.03.131spa
dcterms.referencesWu Q et al (2020) Peculiar synergetic effect of γ-Fe2O3 nanoparticles and graphene oxide on MIL-53 (Fe) for boosting photocatalysis. Chem Eng J 390:124615. https://doi.org/10.1016/j.cej.2020.124615spa
dcterms.referencesZhu L et al (2020) Photo-catalytic pretreatment of biomass for anaerobic digestion using visible light and Nickle oxide (NiOx) nanoparticles prepared by sol gel method. Renew Energy 154:128–135. https://doi.org/10.1016/j.renene.2020.02.119spa
dcterms.referencesVédrine JC (2019) Importance, features and uses of metal oxide catalysts in heterogeneous catalysis. Chinese J Catal 40(11):1627–1636. https://doi.org/10.1016/S1872-2067(18)63162-6spa
dcterms.referencesAl-Dawery SK (2013) Photo-catalyst degradation of tartrazine compound in wastewater using Tio2 and UV light. J Eng Sci Technol 8(6):683–691spa
dcterms.referencesChekir N et al (2017) A comparative study of tartrazine degradation using UV and solar fixed bed reactors. Int J Hydrogen Energy 42(13):8948–8954. https://doi.org/10.1016/j.ijhydene.2016.11.057spa
dcterms.referencesQian R et al (2019) Charge carrier trapping, recombination and transfer during TiO2 photocatalysis: An overview. Catal Today 335:78–90. https://doi.org/10.1016/j.cattod.2018.10.053spa
dcterms.referencesDíez AM et al (2018) A step forward in heterogeneous photocatalysis: Process intensification by using a static mixer as catalyst support. Chem Eng J 343:597–606. https://doi.org/10.1016/j.cej.2018.03.041spa
dcterms.referencesMonteagudo JM, Durán A, Martín IS, Vellón B (2020) Photocatalytic degradation of aniline by solar/TiO2 system in the presence of the electron acceptors Na2S2O8 and H2O2. Sep Purif Technol 238:116456. https://doi.org/10.1016/j.seppur.2019.116456spa
dcterms.referencesKosera VS, Cruz TM, Chaves ES, Tiburtius ERL (2017) Triclosan degradation by heterogeneous photocatalysis using ZnO immobilized in biopolymer as catalyst. J Photochem Photobiol A Chem 344:184–191. https://doi.org/10.1016/j.jphotochem.2017.05.014spa
dcterms.referencesLiu J, Wang Y, Ma J, Peng Y, Wang A (2019) A review on bidirectional analogies between the photocatalysis and antibacterial properties of ZnO. J Alloys Compd 783:898–918. https://doi.org/10.1016/j.jallcom.2018.12.330spa
dcterms.referencesSouza RP et al (2016) Photocatalytic activity of TiO2, ZnO and Nb2O5 applied to degradation of textile wastewater. J Photochem Photobiol A Chem 329:9–17. https://doi.org/10.1016/j.jphotochem.2016.06.013spa
dcterms.referencesÇifçi DI, Meriç S (2015) Optimization of suspended photocatalytic treatment of two biologically treated textile effluents using TiO2 and ZnO catalysts. Glob Nest J 17(4):653–663. https://doi.org/10.30955/gnj.001715spa
dcterms.referencesNomura Y, Fukahori S, Fujiwara T (2020) Removal of 1,4-dioxane from landfill leachate by a rotating advanced oxidation contactor equipped with activated carbon/TiO2 composite sheets. J Hazard Mater 383:121005. https://doi.org/10.1016/j.jhazmat.2019.121005spa
dcterms.referencesGossard A, Lepeytre C (2017) An innovative green process for the depollution of Cr(VI)-contaminated surfaces using TiO2-based photocatalytic gels. J Environ Chem Eng 5(6):5573–5580. https://doi.org/10.1016/j.jece.2017.10.026spa
dcterms.referencesFang Z, Hu Y, Cheng J, Chen Y (2019) Continuous removal of trace bisphenol A from water by high efficacy TiO2 nanotube pillared graphene-based macrostructures in a photocatalytically fluidized bed. Chem Eng J 372:581–589. https://doi.org/10.1016/j.cej.2019.04.129spa
dcterms.referencesde Matos Rodrigues MH et al (2019) “Enhanced degradation of the antibiotic sulfamethoxazole by heterogeneous photocatalysis using Ce0,8Gd0,2O2-δ/TiO2 particles. J. Alloys Compd. https://doi.org/10.1016/j.jallcom.2019.151711spa
dcterms.referencesCastañeda-Juárez M, Martínez-Miranda V, Almazán-Sánchez PT, Linares-Hernández I, Santoyo-Tepole F, Vázquez-Mejía G (2019) Synthesis of TiO2 catalysts doped with Cu, Fe, and Fe/Cu supported on clinoptilolite zeolite by an electrochemical-thermal method for the degradation of diclofenac by heterogeneous photocatalysis. J Photochem Photobiol A Chem 380:111834. https://doi.org/10.1016/j.jphotochem.2019.04.045spa
dcterms.referencesMohan Reddy K, Devaraju J (2019) Kinetics of Photo Fenton Process and Ag-TiO2 Photocatalyst under UV-light”. Mater. Today Proc. 17:235–238. https://doi.org/10.1016/j.matpr.2019.06.424spa
dc.identifier.doi10.1007/s11244-020-01284-1
dc.publisher.placeLuxemburgospa
dc.relation.citationeditionVol. 63, pages1336–1349 (2020)spa
dc.relation.citationendpage1349spa
dc.relation.citationstartpage1336spa
dc.relation.citationvolume63spa
dc.relation.citesBecerra, D., Soto, J., Villamizar, S. et al. Alternative for the Treatment of Leachates Generated in a Landfill of Norte de Santander–Colombia, by Means of the Coupling of a Photocatalytic and Biological Aerobic Process. Top Catal 63, 1336–1349 (2020). https://doi.org/10.1007/s11244-020-01284-1
dc.relation.ispartofjournalTopics in Catalysisspa
dc.rights.accessrightsinfo:eu-repo/semantics/openAccessspa
dc.subject.proposalLeachateseng
dc.subject.proposalTiO2eng
dc.subject.proposalHeterogeneous photocatalysiseng
dc.subject.proposalActivated sludgeeng
dc.subject.proposalZahn Wellens Testeng
dc.type.coarhttp://purl.org/coar/resource_type/c_6501spa
dc.type.contentTextspa
dc.type.driverinfo:eu-repo/semantics/articlespa
dc.type.redcolhttp://purl.org/redcol/resource_type/ARTspa
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oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85spa
dc.type.versioninfo:eu-repo/semantics/publishedVersionspa


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